| Unlockable: | How to Unlock: |
| Aina, Apsalus and High Mobility Zaku I | On Stage 6, have Gundam EZ-8 (Shiro) convince Apsalus (Aina) to become an ally. On Stage 7, do not shoot down the Apsalus. |
| Four | On Stage 16 have Camile convince Four to become an ally. On Stage 18, have Camile to convince her again. Note: You cannot unlock Rosamia if this is done. |
| Kirika | On Stage 24, have a battle sequence with Grendizer DS and Kirika. Shoot down Zuril's Battle Mothership and have Drill Spazer (Maria) convince Kirika to become an ally. |
| Love Love Tenkyouken | On Stage 26, take the Devil Colony route. |
| Minerva X | On Stage 7, keep Ankoku Daishogun and Dragonar-3 alive, then have Mazinger-Z (Kouji) convince Minerva X to become an ally. Note: Minerva X must survive. |
| Rosamia | On Stage 16, have Camile convince Rosamia to become an ally. On Stage 18, have Camile convince her again. Note: You cannot unlock Four if this is done. |
| Unlockable: | How to Unlock: |
| Boss Borot's Pressure Punch | Take the Space route on stage 8(option 1) and have Boss' kill count up to 5 or more before stage 10. |
| Combattler V's Grand Dasher | Take the Nanbara Connection route at the end stage 16(option 1). Combattler V then learns it at stage 28. |
| Daimos' Reppu Seikenzuki Kai | Take the Guinea Highlands route at the end stage 16(option 3). Daimos then learns it at stage 28. |
| Love Love Tenkyouken | Take the Devil Colony route on stage 26(option 1). |
| Voltes V's Choudenji Ball | Take the Big Falcon route at the end stage 16(option 2). Voltes V then learns it at stage 28. |
